https://molmod.ugent.be/publication-authors/s-clerick en https://molmod.ugent.be/publications/heterogeneous-ruiii-oxidation-catalysts-%E2%80%98click%E2%80%99-bidentate-ligands-periodic-mesoporous <div class="field field-name-field-a1-authors field-type-taxonomy-term-reference field-label-hidden"> <span class="field-items"> S. Clerick, E. De Canck, K. Hendrickx, V. Van Speybroeck, P. Van der Voort </span> </div> <div class="field field-name-field-journal-title field-type-taxonomy-term-reference field-label-hidden"> <span class="field-items"> Green Chemistry </span> </div> <div class="field field-name-field-vol-iss field-type-text field-label-hidden"> <div class="field-items"> <div class="field-item even">18, 6035–6045</div> </div> </div> <div class="field field-name-field-a1year field-type-datestamp field-label-hidden"> <div class="field-items"> <div class="field-item even"><span class="date-display-single" property="dc:date" datatype="xsd:dateTime" content="2016-01-01T00:00:00+01:00">2016</span></div> </div> </div> <div class="field field-name-field-a1-type field-type-list-text field-label-hidden"> <div class="field-items"> <div class="field-item even">A1</div> </div> </div> <div class="field field-name-field-not-a-cmm-publication field-type-list-boolean field-label-hidden"> <div class="field-items"> <div class="field-item even"></div> </div> </div> <div class="field field-name-body field-type-text-with-summary field-label-above"> <h3><div class="field-label">Abstract&nbsp;</div></h3> <div class="field-items"> <div class="field-item even" property="content:encoded"><div class="tex2jax"><p>A 100% monoallyl ring-type Periodic Mesoporous Organosilica (PMO) is prepared as a novel, versatile and exceptionally stable catalytic support with a high internal surface area and 5.0 nm pores. Thiol-ene ‘click’ chemistry allows straightforward attachment of bifunctional thiols (-NH2, -OH, -SH) which, exploiting the thioether functionality formed, give rise to ‘solid’ bidentate ligands. [Ru(acac)2(CH3CN)2]PF6 is attached and complex formation on the solid is studied via theoretical calculations. All resulting solid catalysts show high activity and selectivity in alcohol oxidation reactions performed in green conditions (25°C/ water). The PMO catalysts do not leach Ru during reaction and are thus easily recuperated and re-used for several runs. Furthermore, oxidation of poorly water-soluble (±)-menthol illustrates the benefits of using hydrophobic PMOs as catalytic supports.</p> </div></div> </div> </div> <div class="field field-name-field-open-access field-type-list-boolean field-label-hidden"> <div class="field-items"> <div class="field-item even"></div> </div> </div> <div class="field field-name-field-doi field-type-text field-label-above"> <h3><div class="field-label">DOI&nbsp;</div></h3> <div class="field-items"> <div class="field-item even"><div class="tex2jax"><p><a href="http://dx.doi.org/10.1039/C6GC01494A">http://dx.doi.org/10.1039/C6GC01494A</a></p> </div></div> </div> </div> Tue, 31 May 2016 13:55:31 +0000 kevin 4282 at https://molmod.ugent.be https://molmod.ugent.be/publications/heterogeneous-ruiii-oxidation-catalysts-%E2%80%98click%E2%80%99-bidentate-ligands-periodic-mesoporous#comments https://molmod.ugent.be/c1_c3_publications/heterogeneous-ruiii-oxidation-catalysts-%E2%80%98click%E2%80%99-bidentate-ligands-periodic <div class="field field-name-field-a1-authors field-type-taxonomy-term-reference field-label-hidden"> <span class="field-items"> <a href="/publication-authors/s-clerick" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">S. Clerick</a>, <a href="/publication-authors/k-hendrickx" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">K. Hendrickx</a>, <a href="/publication-authors/e-de-canck" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">E. De Canck</a>, <a href="/publication-authors/v-van-speybroeck" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">V. Van Speybroeck</a>, <a href="/publication-authors/p-van-der-voort" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">P. Van der Voort</a> </span> </div> <div class="field field-name-field-isbn-issn field-type-text field-label-hidden"> <div class="field-items"> <div class="field-item even">ISBN/ISSN:</div> </div> </div> <div class="field field-name-field-poster-or-talk field-type-list-text field-label-hidden"> <div class="field-items"> <div class="field-item even">Talk</div> </div> </div> <div class="field field-name-field-conference-name field-type-text field-label-above"> <h3><div class="field-label">Conference / event / venue&nbsp;</div></h3> <div class="field-items"> <div class="field-item even">Multifunctional, Hybrid and Nanomaterials, 5th International conference</div> </div> </div> <div class="field field-name-field-conference-location field-type-text field-label-hidden"> <div class="field-items"> <div class="field-item even">Lisbon, Portugal</div> </div> </div> <div class="field field-name-field-conference-dates field-type-date field-label-hidden"> <div class="field-items"> <div class="field-item even"><span class="date-display-range"><span class="date-display-start" property="dc:date" datatype="xsd:dateTime" content="2017-03-06T00:00:00+01:00">Monday, 6 March, 2017</span> to <span class="date-display-end" property="dc:date" datatype="xsd:dateTime" content="2017-03-10T00:00:00+01:00">Friday, 10 March, 2017</span></span></div> </div> </div> Sun, 30 Jul 2017 10:22:36 +0000 kevin 4853 at https://molmod.ugent.be https://molmod.ugent.be/c1_c3_publications/heterogeneous-ruiii-oxidation-catalysts-%E2%80%98click%E2%80%99-bidentate-ligands-periodic#comments https://molmod.ugent.be/c1_c3_publications/generation-s-containing-bidentate-ligands-periodic-mesoporous-organosilica-pmo <div class="field field-name-field-a1-authors field-type-taxonomy-term-reference field-label-hidden"> <span class="field-items"> <a href="/publication-authors/s-clerick" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">S. Clerick</a>, <a href="/publication-authors/e-de-canck" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">E. De Canck</a>, <a href="/publication-authors/k-hendrickx" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">K. Hendrickx</a>, <a href="/publication-authors/v-van-speybroeck" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">V. Van Speybroeck</a>, <a href="/publication-authors/p-van-der-voort" typeof="skos:Concept" property="rdfs:label skos:prefLabel" datatype="">P. Van der Voort</a> </span> </div> <div class="field field-name-field-isbn-issn field-type-text field-label-hidden"> <div class="field-items"> <div class="field-item even">ISBN/ISSN:</div> </div> </div> <div class="field field-name-field-poster-or-talk field-type-list-text field-label-hidden"> <div class="field-items"> <div class="field-item even">Poster</div> </div> </div> <div class="field field-name-field-conference-name field-type-text field-label-above"> <h3><div class="field-label">Conference / event / venue&nbsp;</div></h3> <div class="field-items"> <div class="field-item even">Doctoral Symposium, Faculty of Sciences</div> </div> </div> <div class="field field-name-field-conference-location field-type-text field-label-hidden"> <div class="field-items"> <div class="field-item even">Ghent</div> </div> </div> <div class="field field-name-field-conference-dates field-type-date field-label-hidden"> <div class="field-items"> <div class="field-item even"><span class="date-display-single" property="dc:date" datatype="xsd:dateTime" content="2016-03-17T00:00:00+01:00">Thursday, 17 March, 2016</span></div> </div> </div> Tue, 22 Mar 2016 15:05:38 +0000 kevin 4210 at https://molmod.ugent.be https://molmod.ugent.be/c1_c3_publications/generation-s-containing-bidentate-ligands-periodic-mesoporous-organosilica-pmo#comments